Ultrafast low-energy electron diffraction (ULEED)

Time-resolved high-energy electron diffraction experiments have unraveled ultrafast structural and electronic processes in bulk media. Ultrafast diffraction with low-energy electrons would be ideal to investigate the structural dynamics of quasi-two-dimensional systems such as ultrathin films and surfaces. However, the realization of such experiments remains demanding, due to the challenges in creating suitable electron pulses [Paarmann et al., 2012].

Our group is working on the development of ultrafast low-energy electron diffraction (ULEED) with first applications in transmission and reflection geometries [Gulde et al., 2014]. Low-energy electron pulses of few-picoseconds duration are generated with a laser-driven tungsten needle emitter and are employed in a laser-pump/electron probe scheme.

In a first application, we studied the structural dynamics of an ordered polymer adsorbate on free-standing graphene by ULEED in transmission [Gulde et al., 2014]. A schematic of our setup is shown in Fig. 1a. We determined the characteristic time scales of the superstructure dynamics, including the energy transfer from the graphene to the adsorbate layer, the loss of crystalline order in the polymer, and the formation of amorphous components at extended spatial frequencies.

Furthermore, we have recently extended ULEED to a backscattering geometry (see fig. 1b) by developing a miniaturized laser-driven photoelectron source. With such a pulsed electron source, we will be able to study complex electronic and structural dynamics at surfaces.

Our research efforts are financially supported by the ERC Starting Grant "ULEED: Observing structural dynamics at surfaces with Ultrafast Low-Energy Electron Diffraction" within "Horizon 2020" since spring 2015 (Project duration 2015-2020).


Selected Publications

"Ultrafast spot-profile LEED of a charge-density wave phase transition"  openaccess
G. Storeck, K. Rossnagel, and C. Ropers
Appl. Phys. Lett. 118(22), 221603 (2021)

 "Strong-field nano-optics"
P. Dombi, Z. Pápa, J. Vogelsang, S. V. Yalunin, M. Sivis, G. Herink, S. Schäfer, P. Groß, C. Ropers, and C. Lienau
Rev. Mod. Phys. 92, 025003-1 (2020)

"Structure and Nonequilibrium Heat-Transfer of a Physisorbed Molecular Layer on Graphene"  openaccess
B. Wit, O. Bunjes, M. Wenderoth, C. Ropers
Adv. Mater. Interfaces 7, 2000473 (2020)

"Structural dynamics of incommensurate charge-density waves tracked by ultrafast low-energy electron diffraction"  openaccess
G. Storeck, J. G. Horstmann, T. Diekmann, S. Vogelgesang, G. von Witte, S. Yalunin, K. Rossnagel, C. Ropers
Struct. Dyn. 7, 034304 (2020)

 "Coherent control of a surface structural phase transition"
J. G. Horstmann, H. Böckmann, B. Wit, F. Kurtz, G. Storeck and C. Ropers
Nature 583, 232-236 (2020) [arXiv]

"Surface structure and stacking of the commensurate (sqrt(13) x sqrt(13))R13.9° charge density wave phase of 1T-TaS2(0001)"
G. von Witte, T. Kißlinger, J. G. Horstmann, K. Rossnagel, M. A. Schneider, C. Ropers, L. Hammer
Phys. Rev. B 100, 155407 (2019)

"Structural dynamics probed by high-coherence electron pulses"
A. Feist, G. Storeck, S. Schaefer, and C. Ropers
MRS Bull. 43, 504-511 (2018)

 "Phase ordering of charge density waves traced by ultrafast low-energy electron diffraction"
S. Vogelgesang, G. Storeck, J. G. Horstmann, T. Diekmann, M. Sivis, S. Schramm, K. Rossnagel, S. Schaefer, C. Ropers
Nat. Phys. 14, 184 (2018) [arXiv]

"Nanotip-based photoelectron microgun for ultrafast LEED"  openaccess
G. Storeck, S. Vogelgesang, M. Sivis, S. Schaefer, C. Ropers
Struct. Dyn. 4, 044024 (2017) [PDF]

"Ultrafast low-energy electron diffraction in transmission resolves polymer/graphene superstructure dynamics"
M. Gulde, S. Schweda, G. Storeck, M. Maiti, H. K. Yu, A. M. Wodtke, S. Schaefer, C. Ropers
Science 345, 200-204 (2014)

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